مطالعه تأثیر حساس‌شدن بر رفتارخوردگی فولاد زنگ‌نزن دوپلکس SAF 2205 در ناحیه ترانس‌پسیو

نوع مقاله: علمی-پژوهشی

نویسندگان

دانشگاه شیراز

چکیده

در این پژوهش، رفتار خوردگی بین دانه‌ای فولاد زنگ‌نزن دوپلکس SAF 2205 در محلول "2 مولار اسید سولفوریک + 1 مولار اسید کلریدریک" در دمای oC 30 با استفاده از آزمون‌های پلاریزاسیون پتانسیودینامیک، راکتیواسیون پتانسیوکینتیک الکتروشیمیایی دو حلقه‌ای (DLEPR)، تفرق اشعه‌ایکس و طیف‌سنجی امپدانس الکتروشیمیایی (EIS) مورد بررسی قرار گرفت. طیف‌سنجی امپدانس الکتروشیمیایی، برای نمونه‌هایی با درجات مختلفی از حساس شدن به مدت 1 و 5 ساعت در دمای oC 725، وجود سه رفتار متفاوت را در پتانسیل های مختلف ناحیه ترانس پسیو نشان داد. نتایج بررسی حاکی از کاهش مقاومت انتقال بار (Rct) و مقاومت پلاریزاسیون (RP) در اثر افزایش زمان حساس‌شدن می‌باشد و این نتایج با تصاویر میکروسکوپ نوری و الکترونی از سطح نمونه‌های خورده‌شده همخوانی دارد.

کلیدواژه‌ها

موضوعات


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